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Kinetics and thermodynamics of the phosphine adsorption on the modified activated carbon

Bingnan REN

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 2,   Pages 203-208 doi: 10.1007/s11705-010-0571-0

Abstract: been explained for the adsorption process of PH .The thermodynamic properties including PH adsorption isotherm and adsorption heat were separately investigatedThe adsorption capacity reached the maximum at 70°C.Then with increasing temperature, chemical adsorption gradually dominated in the adsorption process.The adsorption capacity decreased at above 70°C is due to the exothermic effects in the process of adsorption

Keywords: adsorption     PH<sub>3sub>     activated carbon     kinetics     thermodynamics    

Ammonia adsorption on graphene and graphene oxide: a first-principles study

Yue PENG, Junhua LI

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 403-411 doi: 10.1007/s11783-013-0491-6

Abstract: realization of graphene sensor to detect gas molecules that are harmful to the environment, the ammonia adsorptionThe optimal adsorption and orientation of the NH molecules on the graphene surfaces were determined,and the adsorption energies ( ) as well as the Mulliken charge transfers of NH were calculated.The surface epoxy or hydroxyl groups can promote the adsorption of NH on the GO; the enhancement of

Keywords: graphene oxide     first-principles calculations     NH<sub>3sub> adsorption    

Optimization of electrochemically synthesized Cu

Kasra Pirzadeh, Ali Asghar Ghoreyshi, Mostafa Rahimnejad, Maedeh Mohammadi

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 233-247 doi: 10.1007/s11705-019-1893-1

Abstract: obtained using 1 g of ligand, applied voltage of 25 V, synthesis time of 2 h, and electrode length of 3The isosteric heat of adsorption of both gases was calculated by inserting temperature-dependent formThe adsorption of CO /N binary mixture with a concentration ratio of 15/85 vol-% was also studied experimentallyMoreover, Cu (BTC) showed no considerable loss in CO adsorption after six sequential cycles.

Keywords: Cu<sub>3sub>(BTC)<sub>2sub> electrochemical synthesis     CO<sub>2sub> adsorption     Taguchi optimization    

Utilization of aluminum hydroxide waste generated in fluoride adsorption and coagulation processes for

Jiawei JU,Ruiping LIU,Zan HE,Huijuan LIU,Xiwang ZHANG,Jiuhui QU

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 3,   Pages 467-476 doi: 10.1007/s11783-015-0809-7

Abstract: Although Al-based coagulation and adsorption processes have been proved highly efficient for fluorideThis study aimed to investigate the feasibility of utilizing Al(OH) -F generated in Al(OH) adsorption(Al(OH) -F ) and coagulation (Al(OH) -F ) for the adsorption of cadmium ion (Cd(II)).The adsorption capacity of Al(OH) -F and Al(OH) -F for Cd(II) was similar as that of pristine aluminumThe adsorption of Cd(II) onto Al(OH) -F and Al(OH) -F was identified to be dominated by ion-exchange

Keywords: Al(OH)<sub>3sub>     fluoride     cadmium     adsorption     reclamation     sequential extraction    

Dual-functional sites for synergistic adsorption of Cr(VI) and Sb(V) by polyaniline-TiO hydrate: Adsorption

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 8, doi: 10.1007/s11783-022-1526-7

Abstract:

• PANI/Ti(OH)<sub>nsub>(4n)+ exhibited excellent adsorption capacity and reusability.

Keywords: Polyaniline/TiO<sub>2sub>     Chromium     Antimony     Adsorption     Desorption     Mechanism    

MOF-5@Ni derived ZnO@Ni3ZnC0.7/PMS System for Organic Matter Removal: A Thorough Understanding of theAdsorption−degradation Process Article

Youwen Shuai, Xue Huang, Benyin Zhang, Lu Xiang, Hao Xu, Qian Ye, Jinfeng Lu, Jing Zhang

Engineering 2023, Volume 24, Issue 5,   Pages 254-264 doi: 10.1016/j.eng.2021.08.029

Abstract:

Highlights•[email protected]3ZnC0.7 was successfully synthesized as an effective adsorbent•Surface hydroxyl groups are the key active sites of both adsorption and degradation.•The degradation process regenerates the adsorption capacity of the catalyst.frameworks (MOF)-5 was used as the precursor, and a stable and recyclable material [email protected]3ZnC0.7that exhibited good adsorption and catalytic properties, was obtained by the addition of nickel and

Keywords: MOF-based catalyst     Peroxymonosulfate     Adsorption     Free radical     Non-radical oxidation    

Adsorption characteristics of ciprofloxacin onto g-MoS<sub>2sub><

Zhenyu Yang, Rong Xing, Wenjun Zhou, Lizhong Zhu

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 3, doi: 10.1007/s11783-019-1218-0

Abstract: The coated g-MoS2 greatly increased the adsorption ability of biochar.The synergistic effect was observed for CIP adsorption on g-MoS2-RC700.The adsorption mechanisms of CIP on g-MoS2-BC were proposed.As a result, the g-MoS2-BC composites showed faster adsorption rate and greater adsorption capacity forgreater CIP adsorption capacity than the original biochar.

Keywords: Adsorption     Ciprofloxacin     g-MoS<sub>2sub> nanosheets     Biochar     Soil remediation    

Fabrication of coconut shell-derived porous carbons for CO adsorption application

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 8,   Pages 1122-1130 doi: 10.1007/s11705-022-2292-6

Abstract: >2sub> capture performance.The optimal adsorbent was achieved a high CO<sub>2sub> uptake capacity of 5.92 and 4.15 mmol·gMore importantly, as-prepared carbon adsorbent exhibited moderate isosteric heat of adsorption and highCO<sub>2sub>/N<sub>2sub> selectivity.as a solid-state adsorbent for the CO<sub>2sub> capture.

Keywords: porous carbons     CO<sub>2sub> adsorption     KOH activation     single step reaction     biomass    

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission

Keywords: Rh<sub>2sub>O<sub>3sub>     CePO<sub>4sub>     N<sub>2sub>O decomposition    

Enhanced performance of oxygen vacancies on CO adsorption and activation over different phases of ZrO

Frontiers in Energy 2023, Volume 17, Issue 4,   Pages 545-554 doi: 10.1007/s11708-023-0867-7

Abstract: The effect of oxygen vacancies on the adsorption and activation of CO<sub>2sub> on the surface of differentThe calculations show that the oxygen vacancies contribute greatly to both the adsorption and activationof CO<sub>2sub>.The adsorption energy of CO<sub>2sub> on the c-ZrO<sub>2sub>, t-ZrO<sub>2sub> and, m-ZrO<sub>2sub> surfaces is enhanced to 5, 4, and 3 folds with the help of oxygen vacancies, respectively.

Keywords: CO<sub>2sub> activation     oxygen vacancies     ZrO<sub>2sub>     different phases    

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6,   Pages 63-67

Abstract: lt;/sub>O<sub>3</sub> system with AI<sub>2</sub>O<sub>3</sub>and Cr<sub>2</sub>O<sub>3</sub> diluents were conducted, and the effects of reactionstarting temperature T<sub>O</sub>, diluents AI<sub>2</sub>O<sub>3</sub> and Cr<sub>2</sub>O<sub>3</sub> on the adiabatic combustion temperatureThe near linear relation between T<sub>0</sub> and T<sub>ad</sub> was obtained

Keywords: cermet     combustion synthesis     Al - Cr<sub>2sub>O<sub>3sub> system     thermodynamics     reaction model    

Separation of gibberellic acid (GA3) by macroporous adsorption resins

WANG Ruifang, YANG Jialing, SHI Zuoqing, OU Lailiang

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 2,   Pages 171-175 doi: 10.1007/s11705-008-0025-0

Abstract: The adsorption effects of several macroporous adsorption resins for gibberellic acid (GA3) were investigatedThe dynamic adsorption capacity is 58.38 mg/g dry beads for resin R4 and 96.46 mg/g dry beads for resinAqueous methanol (50%, V/V) is a good eluent and the yield of GA3 is above 95%.The concentration of GA3 could increase five-fold after an adsorption-elution cycle and this is importantwhen considering further crystallization of GA3 in an industrial process.

Keywords: industrial     gibberellic     adsorption capacity     crystallization     consistent    

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Frontiers in Energy 2023, Volume 17, Issue 5,   Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: In this paper, a broad spectrum responsive In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunctionis constructed by in-situ integrating Bi<sub>2sub>S<sub>3sub> with the In<sub>2sub>S<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction demonstrates a rate of 0.71 mmol/(g∙h), which is 2.2 and 1.7 times as much as those of In<sub>2sub>S<sub>3sub> (0.32 mmol/(g∙h) and Bi<sub>2sub>S<sub>3sub> (0.41 mmol/(g∙h)), respectively.

Keywords: photocatalytic hydrogen production     wide-spectrum response     metal sulfides     MOFs derivative     heterogeneous interfacial contact    

Integrated adsorption and absorption process for post-combustion CO

Gongkui Xiao, Penny Xiao, Andrew Hoadley, Paul Webley

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 3,   Pages 483-492 doi: 10.1007/s11705-020-1964-3

Abstract: This study explored the feasibility of integrating an adsorption and solvent scrubbing process for post-combustionThis integrated process has two stages: the first is a vacuum swing adsorption (VSA) process using activatedThe results showed that the adsorption process could enrich CO in the flue gas from 12 to 50 mol-% with

Keywords: vacuum swing adsorption     monoethanolamine     post-combustion     CO<sub>2sub> capture     integrated process    

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al<sub>2sub>O<sub>3sub> with a small amount, wasintroduced into Pb/SiO<sub>2sub> catalyst in this study.It has been proved that Al<sub>2sub>O<sub>3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO<sub>2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O<sub>3sub> addition was also proposed.

Keywords: Pb/SiO<sub>2sub>     Al<sub>2sub>O<sub>3sub>     propane dehydrogenation     propene     stability    

Title Author Date Type Operation

Kinetics and thermodynamics of the phosphine adsorption on the modified activated carbon

Bingnan REN

Journal Article

Ammonia adsorption on graphene and graphene oxide: a first-principles study

Yue PENG, Junhua LI

Journal Article

Optimization of electrochemically synthesized Cu

Kasra Pirzadeh, Ali Asghar Ghoreyshi, Mostafa Rahimnejad, Maedeh Mohammadi

Journal Article

Utilization of aluminum hydroxide waste generated in fluoride adsorption and coagulation processes for

Jiawei JU,Ruiping LIU,Zan HE,Huijuan LIU,Xiwang ZHANG,Jiuhui QU

Journal Article

Dual-functional sites for synergistic adsorption of Cr(VI) and Sb(V) by polyaniline-TiO hydrate: Adsorption

Journal Article

MOF-5@Ni derived ZnO@Ni3ZnC0.7/PMS System for Organic Matter Removal: A Thorough Understanding of theAdsorption−degradation Process

Youwen Shuai, Xue Huang, Benyin Zhang, Lu Xiang, Hao Xu, Qian Ye, Jinfeng Lu, Jing Zhang

Journal Article

Adsorption characteristics of ciprofloxacin onto g-MoS<sub>2sub><

Zhenyu Yang, Rong Xing, Wenjun Zhou, Lizhong Zhu

Journal Article

Fabrication of coconut shell-derived porous carbons for CO adsorption application

Journal Article

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

Enhanced performance of oxygen vacancies on CO adsorption and activation over different phases of ZrO

Journal Article

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Journal Article

Separation of gibberellic acid (GA3) by macroporous adsorption resins

WANG Ruifang, YANG Jialing, SHI Zuoqing, OU Lailiang

Journal Article

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Journal Article

Integrated adsorption and absorption process for post-combustion CO

Gongkui Xiao, Penny Xiao, Andrew Hoadley, Paul Webley

Journal Article

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Journal Article